[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOLIDIN-2-YLIDENE]{2-[[1-(METHOXY(METHYL)AMINO)-1-OXOPROPAN-2-YL]OXY]BENZYLIDENE}RUTHENIUM(II)DICHLORIDEGREENCAT - Names and Identifiers
[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOLIDIN-2-YLIDENE]{2-[[1-(METHOXY(METHYL)AMINO)-1-OXOPROPAN-2-YL]OXY]BENZYLIDENE}RUTHENIUM(II)DICHLORIDEGREENCAT - Physico-chemical Properties
[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOLIDIN-2-YLIDENE]{2-[[1-(METHOXY(METHYL)AMINO)-1-OXOPROPAN-2-YL]OXY]BENZYLIDENE}RUTHENIUM(II)DICHLORIDEGREENCAT - Introduction
[1,3-Bis(2,6-di-i-propylphenyl)imidazolidin-2-ylidene]{2-[[1-(methoxy(methyl)amino)-1-oxopropan-2-yl]oxy]benzylidene}ruthenium(II) dichloride GreenCat (green cat) is a Ru(II) carbene complex of ferrocene and an asymmetric diphenolphthalein stabilizer ligand.
Nature:
-Appearance: Green solid
-Molecular formula: C53H64Cl2N2O3Ru
-Molecular weight: 978.02g/mol
-Melting point: about 120-123°C (with decomposition)
-Solubility: Soluble in organic solvents, such as benzene, toluene, dichloromethane
Use:
-Green cat is an effective carbene ligand catalyst, which is widely used in the cyclization reaction, addition reaction and cross coupling reaction of olefins in organic synthesis.
-It can provide high stereoselectivity and reactivity in homogeneous catalytic reactions.
-can be used for a variety of organic synthesis reactions, such as oxidation, reduction, disproportionation, carboxylation, olefin and benzene cyclization.
Preparation Method:
-The commonly used synthesis method of green cat is through the coordination reaction between the substrate and the ligand.
-The specific synthesis method varies depending on the ligand structure and crystal structure of the green cat.
Safety Information:
-Green cat has certain toxicity, should avoid ingestion or contact with skin, eyes, respiratory tract.
-Wear appropriate personal protective equipment during operation, including chemical protective glasses, chemical protective gloves and protective clothing.
-in use or storage, should be away from fire or high temperature environment.
-Green cats must not be discharged into water sources or the environment, and must comply with appropriate waste disposal rules and regulations.
Last Update:2024-04-10 22:29:15